disulfide catalyzed the highly regioselective conversion of epoxides to halohydrins with elemental halogens

نویسندگان

hossein eshghi

zaiddodine pashandi

gholam hossein rounaghi

afsaneh alipour

azadeh shafaie

چکیده

the regioselective ring opening of styrene oxide using elemental iodine and bromine in the presence of disulfides as new catalysts was studied. the conductivity titration and uv spectroscopy were used to study the interaction of iodine with these catalysts. the results indicate that disulfide 11 is efficient in polyiodide formation, and can catalyze this reaction in excellent yield and high regioselectivity. the complex [(11-disulfide)i]+.i3- is considered to be formed initially which could be bulkier by addition of excess of iodine in the course of the reaction. these bulky nucleophiles have a fundamental role in the high regioselectivity by attacking the less sterically hindered epoxide carbon.

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Disulfide catalyzed the highly regioselective conversion of epoxides to halohydrins with elemental halogens

The regioselective ring opening of styrene oxide using elemental iodine and bromine in the presence of disulfides as new catalysts was studied. The conductivity titration and UV spectroscopy were used to study the interaction of iodine with these catalysts. The results indicate that disulfide 11 is efficient in polyiodide formation, and can catalyze this reaction in excellent yield and high reg...

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Disulfide catalyzed the highly regioselective conversion of epoxides to halohydrins with elemental halogens

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عنوان ژورنال:
iranian journal of catalysis

ناشر: islamic azad university, shahreza branch

ISSN 2252-0236

دوره 4

شماره 1 2014

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